Study on the effect of water contents on the formation of nanostructured porphyrins via self-assembly and their application for the degradation of organic dyes

Anh Nguyen Tuan, Khiem Le Dinh, Quynh Tran Nhu, Tuan Truong Ngoc, Ha Ninh Duc, Phuong Nguyen Thi Hoai, Phuong Nguyen Thi Hong, Lam Tran Dai, Duong La Duc

Abstract


In this work, the THF/H2O mixture was employed to synthesize the nanostrucuted 5,10,15,20-tetra(3,4,5-trimethoxyphenyl) porphyrin (TTOP) via solvophobic self-assembly. The resultant porphyrin nanomaterial was characterized using photoluminescence (PL), UV-vis spectroscopy, and scanning electron microscopy (SEM). The prepared self-assembled porphyrin was in structures of rod-like, cubic-lik, and particles forms. These porphyrin crystals showed high photocatalytic performance for the degradation of RhB under simulated sunlight irradiation, especially with the porphyrin crystal formed with the water fraction of 80 and 90%.

Keywords


Porphyrin; photocatalyst; degradation; supramolecular; self-assembly

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References


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DOI: https://doi.org/10.51316/jca.2021.049

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