Study on synthesis and characterization of nano scale spinel Mn0.5Fe2.5O4 by micro-emulsion method

Ninh Vu The, Loc Dinh Xuan, Tai Tran Anh

Abstract


The single phase of Mn0.5Fe2.5O4 spinel crystals was prepared by the micro-emulsion method with the oil phase is DGDE (diethylene glycol diethyl ether). The characteristics of the materials have been determined by the X-ray diffraction (XRD), Energy-dispersive X-ray spectroscopy (EDX), Scanning electron microscopy (SEM) and Brunaure-Emmet-Teller (BET) nitrogen adsorption and desorption, Vibration sampling magnetometer (VSM), Fourier transform infrared spectroscopy (FTIR). The results showed that the single phase of Fe0.5Mn0.5Fe2O4 crystalline was formed due to the substitution of Fe by Mn in the Fe3O4 crystal lattice and single phase spinel crystal is formed with the size of 6.7 nm, specific surface area ≈ 193 m2.g-1, the saturation magnetization reaches ≈ 27 emu.g-1.

Keywords


Mn0.5Fe2.5O4; micro-emulsion; DGDE; magnetic properties; nano scale

Full Text:

PDF

References


Phan Van Tuong, Inorganic Materials, Hanoi national university publisher, Vietnam, 1998.

Merzhanov A. G., Theory and Practice of SHS: Worldwide state of the art and Newest Results, International Journal of Self Propagating High Temperature, 2(2), (1993) 113-158. https://doi.org/10.3103/S1061386213040110

Jiang Q.L., Zheng S.W., Hong R.Y., et al., Folic acid-conjugated Fe3O4 magnetic nanoparticles for hyperthermia and MRI in vitro and in vivo, Applied Surface Science, 307, (2014) 224-233. https://doi.org/10.1016/j.apsusc.2014.04.018

Sumuel C.N.T., Irene M.C.L., Magnetic nanoparticles: essential factors for sustainable environmental applications, Water Research, 47(8), (2013) 2613-2632. https://doi.org/10.1016/j.watres.2013.02.039

Jozef S., Martin S., Anna G., et al., Magnetic properties of selected substituted spinel ferrites, Journal of Magnetism and magnetic Materials, 326, (2013) 251-256. https://doi.org/10.1016/j.jmmm.2012.07.016

Akin I., Arslan G., Tor A., et al., Arsenic(V) removal from underground water by magnetic nanoparticles synthesized from waste red mud, Journal of Hazardous Materials, 235-236, (2012) 62-68. https://doi.org/10.1016/j.jhazmat.2012.06.024

Trung V.Q., Trang N.T.H., Thi T.M., et al., Synthesis and Properties of Fe3O4/Polyaniline Nanomaterial and Its Ability of Removing Arsenic in Wastewater, Materials Transactions, 59(7), (2018) 1095-1100. https://doi.org/10.2320/matertrans.md201703

Babu C.M., Palanisamy B., Sundaravel B., et al., Magnetic Fe3O4/SiO2 Core-Shell Nanorods for the Removal of Arsenic, Journal of Nanoscience and Nanotechnology, 13, (2013) 2517-2527. https://doi.org/ 10.1166/jnn.2017376

Shuang Z., Jun Y., Xiaoyan Q., et al., Magnetically recyclable MnFe2O4/polyaniline composite with enhanced visible light photo catalytic activity for rhodamine B degradation, Journal of the Ceramic Society of Japan, 124(10), (2016) 1152-1156. https://doi.org/10.2109/jcersj2.16056

Cai Y., Zeng G., Guo P., et al., Effective removal of Cr(VI) through adsorption and reduction by magnetic mesoporous carbon incorporated with polyaniline, Royal Society of Chemistry Advances, 4(102), (2014) 58362-58371. https://doi.org/10.1039/C4RA08432B

Jae G.L., Jung H.K., Kwang P.C., Crystallographic and Magnetic Properties of Zn-Mn Ferrite, Journal of the Korean Physical Society, 49(2), (2006) 604-607.

Tripathy D., Adeyeye A.O., Boothroyd C.B., Shannigrahi S., Microstructure and magnetotransport properties of Cu doped Fe3O4 films, Journal of Appied Physics, 103, (2008) 07F701-07F703. https://doi.org/ 10.1063/1.2828504

Giri J., Pradhan P., Somani V., et al., Synthesis and characterizations of water-based ferrofluids of substituted ferrites [Fe1-xBxFe2O4, B = Mn, Co (x = 0-1)] for biomedical applications, Journal of Magnetism and Magnetic Materials, 320, (2008) 724-730. https://doi.org/10.1016/j.jmmm.2007.08.010

Zhang S., Niu H., Cai Y., et al., Arsenite and arsenate adsorption on co-precipitated bimetal oxide magnetic nanomaterials: MnFe2O4 and CoFe2O4, Chemical Engineering Journal, 158, (2010) 599-607. https://doi.org/10.1016/j.cej.2010.02.013

Huong P.T.L., Tu N., Lan H., et al., Functional manganese ferrite/graphene oxide nanocomposites: effects of graphene oxide on the adsorption mechanisms of organic MB dye and inorganic As(V) ions from aqueous solution, Royal Society of Chemistry Advances, 8, (2018) 12376-12389. https://doi.org/10.1039/c8ra00270c

Wang L., Li J., Wang Y., et al., Adsorption capability for Congo red on nanocrystalline MFe2O4 (M = Mn, Fe, Co, Ni) spinel ferrites. Chemical Engineering Journal, 181-182, (2012) 72-79. https://doi.org/10.1016/j.cej.2011.10.088

Hu J., Lo I.M.C., Chen G.H., Comparative study of various magnetic nanoparticles for Cr(VI) removal, Separation and Purification Technology, 56, (2007) 249-256. https://doi.org/10.1016/j.seppur.2007.02.009

Okoli C., Sanchez-Dominguez M., Boutonnet M., et al., Comparison and Functionalization Study of Microemulsion-Prepared Magnetic Iron Oxide Nanoparticles, Langmuir, 28(22), (2012) 8479-8485. https://doi.org/10.1021/la300599q

Kale S.N., Deore S.L., Emulsion Micro Emulsion and Nano Emulsion: A Review, Systematic Reviews in Pharmacy, 8(1), (2017) 39-47. https://doi.org/10.5530/srp.2017.1.8

Yadav V., Jadhav P., Kanase K., et al., Preparation and evaluation of microemulsion containing antihypertensive drug, International Journal of Applied Pharmaceutics, 2018, 10(5), 138-146. https://doi.org/10.22159/ijap.2018v10i5.27415

Loc D.X., Huyen T.T.T., Loan N.T., et al., Synthesis and adsorption ability of Cr2Fe2O4 spinel nanomaterials for the removal of heavy metal ions and organic dyes from industrial and domestic wastewater, Vietnam Journal of Chemistry, 57(4e12), (2019) 426-430.

Nam P.H., Phong P.T., Mạnh D.H., Study the structure and magnetic properties of Co1-xZnxFe2O4 (x = 0.0-0.7) nanoparticle system fabricated by thermal decomposition method, Vietnam Journal of Science and Technology, 54(1A), (2016) 25-32.

Nam P.H., Uyen L.L., Thuy D.M., Manh D.H., et al., Dynamic effects of dipolar interactions on the specific loss power of Mn0.7Zn0.3Fe2O4, Vietnam Journal of Science and Technology, 56(1A), (2018) 50-58.

Loan N.T.T., Dai L.M., Synthesis of nano scale CoFe2O4 by gel combustion method, Vietnam Journal of Chemistry, 48(4), (2010) 404-408.

Https://pubchem.ncbi.nlm.nih.gov/compound/Diethylene-glycol-diethyl-ether.

Ninh V.T., Nhiem D.N., Anh N.T., Dai L.M., Preparation of nano-sized La2O3-Fe2O3-Mn2O3 mixed oxides for As(V) adsorption from solution, Vietnam Journal of Chemistry 55(3e12), (2017) 245-249.




DOI: https://doi.org/10.51316/jca.2020.066

Refbacks

  • There are currently no refbacks.




*******

Index: Google ScholarCrossref

---------

Vietnam Journal of Catalysis and Adsorption

Address: Room 302  |  C4-5  |  Hanoi University of Science and Technology. 1 Dai Co Viet, Hanoi.

Tel.: ‎‎‎+84. 967.117.098 (Dr. Phượng)   Email: editor@jca.edu.vn   FB: JCA.VNACA