Green synthesis of metal-organic framework materials MOF-199 and its adsorption of organic solvents gas

Hanh Thu Thi Pham, Phuong Hoai Thi Nguyen

Abstract


This study synthesized the copper benzene-1,3,5-tricarboxylate metal-organic framework (Cu-BTC) by the hydrothermal method in mixed solvent water/ethanol/PEG. The formed MOF-199 material has a uniform, sharp, octahedral crystal morphology with a 5 ÷ 8 µm size. The surface area of MOF-199 with the BET model is 1.360,76 m2/g. This material can adsorb volatile organic compounds with high capacity. The saturation adsorption capacity of MOF-199 with ethanol, acetone, benzene, toluene, and butyl acetate was 99,50; 86,80; 91,00; 79,00; 104,50 mg/g, respectively. The regenerative capacity of the material also showed that the material was resistant to volatile organic solvents when used 7 times in a row, only decreased under 10%.


Keywords


Metal-organic frameworks; copper benzene-1,3,5-tricarboxylate; organic solvent; adsorption

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References


P. M. Trang, Tạp chí Hoạt động Khoa học công nghệ An toàn - Sức khoẻ và Môi trường lao động 1,2&3, (2021) 50-56.

H.L. Phương, Tạp chí Y học Việt Nam 514 (2022) 31-39.

N. D. Bảo, Tạp chí Y học dự phòng, XXIII(3) (2013) 103-109.

N. V. Sơn, Tạp chí Sức khoẻ & Môi trường 27 (2015) 18-22.

N. T. Hương, V. H. Phương, N. V. Hưng, N. Đ. Dương, N. N. Sơn, P. T. Anh, Tạp chí Nghiên cứu Khoa học và Công nghệ quân sự 45 (2016) 154-160.

E. Dumont, A. Couvert, A. Amrane, C. Couriol, G. Darracq, P. Le Cloirec, Chemical Engineering Journal 287 (2016) 205-216. http://dx.doi.org/10.1016/j.cej.2015.11.020

C. Chen, Y. Huang, S. Hung, C. Chen, C. Lin, H. Yang, Chemical Engineering Journal 424 (2021) 130420. https://doi.org/10.1016/j.cej.2021.130420

H. T. T. Vân, Tạp chí Môi trường CD2 (2022) 84-87.

L. Wei, C. Yu, K. Yang, Q. Fan, H. Ji, Chinese Journal of Catalysis 42 (2021) 1078-1095. https://doi.org/10.1016/S1872-2067(20)63721-4

Z. Li, J. Liu, B. Gao, L. Bo, Chemical Engineering Journal 442 (2022) 136288. https://doi.org/10.1016/j.cej.2022.136288

M. Marycz, A. B. Dąbrowska, S. Cantera, J. Gebicki, R. Muñoz, Chemosphere 313 (2023) 137609. https://doi.org/10.1016/j.chemosphere.2022.137609

M. Schiavon, M. Scapinello, P. Tosi, M. Ragazzi, V. Torretta, E. C. Rada, Journal of Cleaner Production 104 (2015) 211-219. http://dx.doi.org/10.1016/j.jclepro.2015.05.034

A. V. Fernández, F. Scott, P. M. Casas, L. D. Robles, R. Muñoz, Chemosphere 157 (2016) 89-96. http://dx.doi.org/10.1016/j.chemosphere.2016.05.034

E. Wantz, A. Kane, M. Lhuissier, A. Amrane, J. L. Audic, A. Couvert, Chemical Engineering Journal 423 (2021) 130106. https://doi.org/10.1016/j.cej.2021.130106

M. Lhuissier, A. Couvert, A. Amrane, A. Kane, J. L. Audic, Chemical Engineering Research and Design 138 (2018) 482-489. https://doi.org/10.1016/j.cherd.2018.08.028

M. Sansotera, S. Geran, M. Kheyli, A. Baggioli, C. L. Bianchi, M. P. Pedeferri, M. V. Diamanti, W. Navarrini, Chemical Engineering Journal 361 (2019) 885-896. https://doi.org/10.1016/j.cej.2018.12.136

O. M. Yaghi, C. E. Davis, G. Li, H. Li, American Chemical Society 119(12) (1997) 2861-2868.

S. Soni, P. K. Bajpai, C. Arora, Characterization and Application of Nanomaterials 2 (2019) 1-20. https://doi: 10.24294/can.v2i2.551

H. Li, L. Li, R. B. Lin, W. Zhou, Z. Zhang, S. Xiang, B. Chen, EnergyChem 1(1) (2019) 100006. https://doi.org/10.1016/j.enchem.2019.100006

D. P. Pathak, Y. Kumar, S. Yadav, Sustainable Materials for Sensing and Remediation of Noxious Pollutants Chapter 4 (2022) 47-64. https://doi.org/10.1016/B978-0-323-99425-5.00002-5

M. S. Alhumaimess, Journal of Saudi Chemical Society 24(6) (2020) 461-473. https://doi.org/10.1016/j.jscs.2020.04.002

S. Mallakpour, E. Nikkhoo, C. M. Hussain, Coordination Chemistry Reviews 451 (2022) 214262. https://doi.org/10.1016/j.ccr.2021.214262

Z. Wang, Y. Zhong, C. Wei, L. Jiang, H. Liu, Journal of The Electrochemical Society 169(1) 010516. https://10.1149/1945-7111/ac4841

N. M. Mahmoodi, J. Abdi, Microchemical Journal 144 (2019) 436-442. https://doi.org/10.1016/j.microc.2018.09.033

S. Fan, H. Guo, Y. Wang, J. Liu, Journal of the Indian Chemical Society 99 (2022) 100579. https://doi.org/10.1016/j.jics.2022.100579

C. Xue, J. Wang, W. Zhao, R. Huang, Y. Wei, T. Wu, Y. Lin, K. Lv, X. Li, X. Hao, Microporous and Mesoporous Materials 328 (2021) 111510. https://doi.org/10.1016/j.micromeso.2021.111510

N. T. H. Phuong, N. D. Ha, Vietnam Journal of Science and Technology 53 (2015) 320-326.

H. Y. Zhanga, C. Yanga, Q. Genga, H. L. Fan, B. J. Wang, M. M. Wua, Applied Surface Science 497 (2019) 143815. https://doi.org/10.1016/j.apsusc.2019.143815

B. Ouyang, F. Liu, C. Liang, J. Zhang, R. Hu, H. Yuan, R. Hai, Y. Yuan, X. Wu, S. T. Yang, Science of the Total Environment 813 (2022) 151912. http://dx.doi.org/10.1016/j.scitotenv.2021.151912

S. Z. H. Kiadeh, A. Ghaee, M. Farokhi, J. Nourmohammadi, A. Bahi, F. K. Ko, International Journal of Biological Macromolecules 173 (2021) 351-365. https://doi.org/10.1016/j.ijbiomac.2021.01.058

B. Anand, K.H. Kim, R.K. Sonwani, J.E. Szulejko, P.M. Heynderickx, Environmental Research 208 (2022) 112655. https://doi.org/10.1016/j.envres.2021.112655.

M.S. Hosseini, S. Zeinali, M.H. Sheikhi, Sensors and Actuators B: Chemical 230 (2016) 9-16. http://dx.doi.org/10.1016/j.snb.2016.02.008.

S. S. Y. Chui, S. M. F. Lo, J. P. H. Charmant, A. G. Orpen, I. D. Williams, Science 283(5405) (1999) 1148-1150. https://10.1126/science.283.5405.1

N. Đ. Hà, T. T. N. Hiếu, N. T. H. Phương, Tạp chí Hóa học 53(4E1) (2015) 29-32.




DOI: https://doi.org/10.51316/jca.2023.057

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