Adsorption of Iodide (I-) from aqueous solution onto biochar derived from pomelo fruit peel

Ngoc Bich Duong, Khoi Duy Nguyen, Hoang Thien Ho, Loc That Ton, An Ngoc Nguyen, Tuyen Kim Nguyen Pham, Chi Linh Bui Huynh, Nham Thuy Thi Nguyen, Tuan Anh Hoang, Phuc Van Dinh

Abstract


Removing iodide from aqueous solution using biomaterials synthesized from pomelo fruit peel-derived biochar with low costs is a new approach in environmental science and application. The material was characterized by various analytic methods such as XRD, SEM, BET, and FTIR. Additionally, Leuco crystal violet method was used to ascertain the quantity of iodide (I-) adsorbed and UV-Vis spectroscopy was used to quantify it. The effects of pH (2–11) and interaction duration (3–42 h) on the iodide adsorption were carefully examined. To examine the isotherm and dynamic characteristics of the substance, the Langmuir, Freundlich, pseudo-first-order, pseudo-second-order, and in-diffusion models were applied. The results showed that the maximum adsorption took place at pH 2 for 2520 min and the adsorption followed the intra-diffusion kinetic model as well as the maximum capacity (qm) derived from the Langmuir equation was 7,06 mg/g at 303 K, this number is higher than the maximum uptake capacity based on experiment findings (qe = 1,46 mg/g).

Keywords


Biochar; pomelo fruit; Iodide (I-) adsorption; isotherm; kinetic properties

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DOI: https://doi.org/10.51316/jca.2023.022

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