Synthesis of molybdenum disulfide for the hydrogen evolution reaction electrocatalysts activity by electrochemical method

Thuy Mai Thi Thanh, Van-Anh Nguyen Thi, Xuan Mai Thi, Binh Phan Thi

Abstract


This research aims to synthesize MoS2 thin film for the hydrogen evolution reaction (HER) by the electrochemical way. We investigated various electrochemical conditions, including the pH of electrolyte, the applied current density, and electrolysis time to find optimal synthesis mode. The obtained samples were characterized by scanning electron microscopy (SEM) images and X-ray diffraction (XRD) patterns to determine the morphology and crystal structure. The polarization curve confirmed the HER activity of MoS2 thin film. The results indicated that the synthesized MoS2 film had a perfect catalytic activity, as shown by the overpotential value at 10 mA/cm2 and Tafel slope reached 144 mV and 56.2 mV/dec, respectively.


Keywords


Thiomolybdates solution; Electrodeposition; HER; Molybdenum disulfide

Full Text:

PDF

References


T.Bak, J. Nowotny ,M. Rekas, C.C. Sorrell, Inter. J. of Hydrogen Energy 27 (2002) 991 – 1022. https://doi.org/10.1016/S0360-3199(02)00022-8.

Qi Ding, Bo Song, Ping Xu, Song Jin, Chem, 1 (2016) 699-726. https://doi.org/10.1016/j.chempr.2016.10.007

Uttam Gupta, C.N.R.Rao, Nano energy, 41 (2017) 49-65. https://doi.org/10.1016/j.nanoen.2017.08.021

Effat Sitara , Habib Nasir , Asad Mumtaz , Muhammad Fahad Ehsan , Manzar Sohail, Sadia Iram, Syeda Aqsa Batool Bukhari, Nanomaterials, 10 (2020) 2341. https://doi.org/10.3390/nano10122341

F. Mak, C. Lee, J. Hone, J. Shan, T.F. Heinz, Phys. Rev. Lett, 105 (2010) 136805–136808. https://10.1103/PhysRevLett.105.136805

Vesborg P.C.K, Seger B, And Chorkendorff I, J. Phys. Chem. Lett., 6 (2015) 951–957. https://doi.org/10.1021/acs.jpclett.5b00306

Popczun E.J, Mckone J.R, Read, C.G, Biacchi A.J, Wiltrout A.M, Lewis N.S, And Schaak R.E, J. Am. Chem. Soc, 135 (2013) 9267–9270. https://doi.org/10.1021/ja403440e

Callejas J.F, Read C.G, Roske C.W, Lewis N.S, And Schaak R.E, 28 (2016) 6027–6044. https://doi.org/10.1021/acs.chemmater.6b02148

Caban-Acevedo M, Stone M.L, Schmidt J.R, Thomas J.G, Ding Q, Chang H.C, Tsai M.L, He J.H, Jin S, Nat. Mater,14 (2015) 1245–1251. https://doi.org/10.1038/nmat4410

Jaramillo T.F, Jorgensen K.P, Bonde J, Nielsen J.H, Horch S, And Chorkendorff I, Science, 317 (2007) 100-102. https://10.1126/science.1141483.

Hinnemann B, Moses P.G, Bonde J, Jorgensen K.P, Nielsen J.H, Horch S, Chorkendorff I, Norskov J.K, J. Am. Chem. Soc, 127 (2015) 5308–5309. https://doi.org/10.1021/ja0504690

Zhenhua Lou, Di Wu, Kun Bu, Tingting Xu, Zhifeng Shi, Junmin Xu, Yongtao Tian, Xinjian Li, Journal of alloys and compounds, 726 (2017) 632- 637. https://doi.org/10.1016/j.jallcom.2017.07.338

Nahid Chaudhary, Manika Khanuja, Abid, S.S. Islam, Sensors and actuators A, 277 (2018) 190–198. https://doi.org/10.1016/j.sna.2018.05.008

Lijuan Ye, Haiyan Xu, , Shijian Chen, Material reseach bulletin, 55 (2014) 221-228. https://doi.org/10.1016/j.materresbull.2014.04.025

Shuang Liu, Changbin Nie, Dahua Zhou, Jun Shen, Shuanglong Feng, Physica E: low-dimensional systems and nanostructures, 117 (2020) 113592. https://doi.org/10.1016/j.physe.2019.113592

Jie Zhang, Tianyu Liu, Liangjie Fu, Gonglan Ye, Chemical physics letters, 781 (2021) 138972. https://doi.org/10.1016/j.cplett.2021.138972

Akif Shikhan Aliyev, Mahmoud Elrouby, Samira Fikret Cafarova, Materials science in semiconductor processing, 32, (2015) 31–39. https://doi.org/10.1016/j.mssp.2015.01.006

Megha Shrivastava, Reeta Kumari, Mohammad Ramzan Parra, Padmini Pandey, Hafsa Siddiqui, Fozia Z. Haque, Optical material, 73 (2017) 763-771. https://10.1016/j.optmat.2017.09.029

Lina Zhang, Liangliu Wu, Jing Li And Jinglei Lei, BMC chemistry,13:88 (2019) https://doi.org/10.1186/s13065-019-0600-0

Tzu Hsuan Chiang, Hung Che Yeh, Materials, 6 (2013) 4609-4625. https://10.3390/ma6104609

S.K. Ghosha, T. Bera, O. Karacasua, A. Swarnakar, J.G. Buijnsters, J.P. Celis, Electrochimica Acta, 56 (2011) 2433-2442.

https://10.1016/j.electacta.2010.10.065

Pravas Kumar Panigrahi, Amita Pathak, Journal of Nanoparticles, 2013, 671214. https://doi.org/10.1155/2013/671214

Tuhin Subhra Sahu, Sagar Mitra , Scientific Reports, 5 (2015) 12571. https://doi.org/10.1038/srep12571

Xia Li, Bo Wang, Xia Shu, Dongmei Wang, Guangqing Xu, Xinyi Zhang, Jun Lv, Yucheng Wu, RSC Advances, 9 (2019) 15900–15909. https://doi.org/10.1039/C8RA09806A

Xin-Wei Yang, Xiao-Ping Wang, Li-Jun Wang, Diamond and Related Materials, 114 (2021) 108331. https://doi.org/10.1016/j.diamond.2021.108331

Kai Xia, Meiyu Cong, Fanfan Xu, Xin Ding, and Xiaodong Zhang, Nanomaterials, 10 (2020) 1547. https://doi.org/10.3390/nano10081547

Xuebin Houa, Alfred Mensaha, Min Zhaoa, Yibing Caia, Qufu Wei, Applied surface science, 529 (2020) 147115. https://10.1016/j.apsusc.2020.147115

Chia Chin cheng, Ang Yu Lu, Chien Chih Tseng, Xiulin Yang, Mohamed Nejib Hedhili, Min Cheng Chen, Kung Hwa Wei, Lain Jong Li, Nano energy, 30 (2016) 846-852. https://doi.org/10.1016/j.nanoen.2016.09.010

Shasha Li, Suchada Sirisomboonchai, Xiaowei An, Xuli Ma, Peng Li, Lixia Ling, Xiaogang Hao, Abuliti Abudula, Guoqing Guan, Nanoscale, 12 (2020) 6810-6820. https://doi.org/10.1039/D0NR00008F

Ruimin Ding, Mengchao Wang, Xianfen Wang, Huixiang Wang, Liancheng Wang, Yuewen Mu, Baoliang Lv , Nanoscale, 11 (2019) 11217-11226. https://doi.org/10.1039/C9NR02717C

Wen Li, Jun-wei Chen, Zong-liang Xiao, Jing-bo Xing, Chen Yang, Xiao-peng Qi, New Carbon Materials, 35 (2020) 540-546. https://10.1016/S1872-5805(20)60507-8

Zhiwen Chen, Xiao Liu, Peijun Xin, Haitao Wang, Ye Wu, Chunyan Gao, Qingquan He, Yong Jiang, Zhangjun Hu, Shoushuang Huang, Journal of Alloys and Compounds, 853 (2021) 157352. https://doi.org/10.1016/j.jallcom.2020.157352

Huan Chen, Haichao Jiang, Xuepu Cao, Yantao Zhang, Xiangjing Zhang, Shanlin Qiao, Materials Chemistry and Physics, 252 (2020) 123244. https://doi.org/10.1016/j.matchemphys.2020.123244

Mingwei Hu, Jin Huang, Qizhong Li, Rong Tu, Song Zhang, Meijun Yang, Haiwen Li, Takashi Goto, Lianmeng Zhang, Journal of Alloys and Compounds, 827 (2020) 154262. https://doi.org/10.1016/j.jallcom.2020.154262




DOI: https://doi.org/10.51316/jca.2022.037

Refbacks

  • There are currently no refbacks.




*******

Index: Google Scholar; Crossref

---------

Vietnam Journal of Catalysis and Adsorption

Address: Room 302  |  C4-5  |  Hanoi University of Science and Technology. 1 Dai Co Viet, Hanoi.

Tel.: ‎‎‎+84. 967.117.098 (Dr. Phượng)  |  Email: editor@jca.edu.vn  |  FB: JCA.VNACA