Reduction of 4-nitrophenol to 4-aminophenol using Pt/HKUST-1 catalyst

Ha Bui Thi Thanh, Duong Le Van, Hung Ta Ngoc, Hai Dinh Thi Thanh, Duong Pham Dai, Anh Nguyen Le, Don Ta Ngoc

Abstract


The catalyst Pt/HKHUST-1 was used for synthesis 4-aminophenol (4-AP) by reducsion 4-nitrophenol (4-NP). Factors that affected to the reaction were tested: ratio 4-NP/NaBH4, temperature and time of the reaction. Changing the ratio of 4-NP/NaBH4 in the direction of increasing NaBH4, the reaction rate increases. However, it is acceptable to reduce the reaction rate when synthesizing with high concentration of reactants. The 4-AP synthesis is performed with ratio 4-NP/NaBH4 = 1/5, suitable time and temperature for this reaction is 60 minutes and 15 oC. The catalyst sample containing 2% Pt on HKUST-1 material was used to synthesize 4-AP with the yield of 65.3% (average 64.2%), the catalyst has good stability, can reused many times. The purity of 4-AP after refining was > 99 %.


Keywords


HKUST-1; MOFS-199; Metal Organic Frameworks; 4-nitrophenol; NaBH4; 4-aminophenol; paracetamol

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DOI: https://doi.org/10.51316/jca.2022.017

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