Application of adsorbents based on LaFe1-xMnxO3 perovskites to treat As, Pb in contaminated groundwater in the craft village

Ninh Vu The, Dung Nguyen Viet, Dai Luu Minh, Anh Nguyen Thanh

Abstract


The nanoparticle crystals of perovskite LaFe1-xMnxO3 were prepared by the PVA (polyvinyl alcohol) gel combustion method to determine the adsorption capacity of As(V), Pb2+ from solution was investigated. Single-phase crystalline perovskite of LaFe1-xMnxO3 is formed by solid solution formation which completely replaces LaFeO3 perovskite and LaMnO3 perovskite. In LaFe1-xMnxO3 perovskites, the x substitution composition, or the rate of participation to form the substitution solid solution between the two components LaFeO3 and LaMnO3 will determine the type of original structure, the interaction between the Fe and Mn in in the crystal lattice. Thereby determining the characteristics and adsorption activity of perovskite LaFe1-xMnxO3. Perovskite LaFe1-xMnxO3 with the formula LaFe0.3Mn0.7O3 gave the best As(V) adsorption efficiency on the x components, while the LaFe0.7Mn0.3O3 formula gave the best As(V) adsorption efficiency on the x components. The LaFe1-xMnxO3 perovskite-based adsorbent pelletized with the composition LaFe0.3Mn0.7O3-LaFe0.7Mn0.3O3-bentonite has practical potential to remove arsenic, lead in contaminated water.

Keywords


Perovskite LaFe1-xMnxO3; arsenic-lead adsorption; contaminated groundwater; craft village.

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References


M. Branislava, L. Vesna, N. Đorđe, V. Ljubinka, J. Serb. Chem. Soc., 76(10) (2011) 1437-1452. DOI: 10.2298/JSC101029122J.

World Health Organization. Guidelines for Drinking-water Quality, WHO Press, Third Edition Incorporating The First And Second Addenda, 2008. DOI: 10.1016/j.jmmm.2007.08.010.

A. Khan, S. Rasul, A. Munir, M. Habibuddowla, M. Alauddin, S. Newaz, A. Hussan, J. Environ. Sci. Health, 35(7) (2000) 1021-1041. DOI:10.2320/MATERTRANS.MD201703.

WHO/UNICEFF. Meeting the fundamental need for water, sanitation and hygiene services in health care facilities, Global meeting held Madrid, 2015.

L. Rajaković, Faculty of Technology and Metallurgy, PhD Thesis, University of Belgrade, Belgrade, 1986.

K. Chakresh, A. Imran, Water Reseach, 34(17) (2000) 4304-4312. DOI:10.1016/s0043-1354(00)00182-2.

D. Wolfgang, S. Reiner, J. Martin, Water Research, 29(1) (1995) 297-305. DOI: 10.1016/0043-1354(94)e0089-o.

J. Giménez, M. Martínez, J. dePablo, M. Rovira, L. Duro, Journal of Hazardous Materials, 2007, 141, 575-580. DOI: 10.2109/jcersj2.16056.

Moore J.N., Walker J.R., Hayes T.H., Reaction scheme for the oxidation of As (III) to arsenic (V) by birnessite, Clays Clay Miner, 1990, 38, 549-555.

S. Tokunaga, S. Wasay, S. Park, Water Science Technology, 35(7) (1997) 71-78. DOI: 10.1016/s0273-1223(97)00116-9.

Luu Minh Dai, Nguyen Thi To Loan, Dao Ngoc Nhiem, Vu The Ninh. Synthesis of MnO2 nano-scale by gel combustion method and study the possibility of using nano MnO2 for arsenic adsorption, Vietnam Journal of Chemistry, 46(2A) (2008) 43-49.

J. Lai, K. Shafi, V. Kurikka, A. Ulman, The Journal of Physical Chemistry B, 108(39) (2004) 14876–14883. DOI:10.1021/jp049913w.

Vu The Ninh, Dao Ngoc Nhiem. Fabrication of LaFe1-xMnxO3 perovskite perovskite complex nano-oxides for As(V) adsorption from solution, Vietnam Journal of Chemistry, 56(6E1) (2018) 217-222.

Vu The Ninh, Pham Ngoc Chuc, Luu Minh Dai. Fabrication and characterization of LaFe1-xMnxO3 nanoperovskite nanostructures (0 ≤x≤ 1) as adsorbent materials to treat water pollution, Vietnam Journal of Catalytic Adsorption, 8(2) (2019) 92-97.

Nguyen Huu Phu. Textbook of Physical Chemistry, Hanoi Science and Technology Publishing House, 2000.




DOI: https://doi.org/10.51316/jca.2021.126

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