O3-type layered Ni-rich cathode: synthesis and electrochemical characterization

Minh Nguyen Le, Hoang Nguyen Van, Trang Bach Le Thuy, Man Tran Van, Phung Le My Loan

Abstract


Ni-rich layered oxides are currently the state-of-the-art material of Lithium-ion batteries due to the balance between the cost, power and energy density. In this work, Ni-rich O3-type NaxNi0.76Mn0.14Co0.10O2.04 (NMC) material was synthesized by the conventional solid-state reaction and investigated as a cathode material for sodium-ion batteries. Rietveld refinement shows that the material is high purity O3-type layered oxide of >91%.  In the charge/discharge test, the material was provided the reversible capacity of 156 mAh.g-1 initially at 0.1 C with 50% capacity retention after 50 cycles in the voltage range of 2.0 – 4.2 V. In addition, this material also demonstrates great rate-capability with the discharge capacity of 50 mAh.g-1 even at 5 C. Therefore, NMC material could be a promising candidate for high energy sodium-ion batteries.

Keywords


Cathode material; diffusion coefficient; Na-ion batteries; Ni-rich; O3-type

Full Text:

PDF

References


D. Larcher, J. -M. Tarascon, Nat. Chem. 7 (2015) 19–29. https://doi.org/10.1038/nchem.2085

H. Pan, Y. -S. Hu, L. Chen, Energy Environ. Sci. 6 (2013) 2338–2360. https://doi.org/10.1039/C3EE40847G

S. Y. Hong, Y. Kim, Y. Park, A. Choi, N. -S. Choi, K. T. Lee, Energy Environ. Sci. 6 (2013) 2067–2081. https://doi.org/10.1039/C3EE40811F

P. Vassilaras, X. Ma, X. Li, G. Ceder, J. Electrochem. Soc. 160 (2012) A207. https://doi.org/10.1149/2.023302jes

J. -Y. Hwang, C. S. Yoon, I. Belharouak, Y. -K. Sun, J. Mater. Chem. A 4 (2016) 17952–17959. https://doi.org/10.1039/C6TA07392A

M. Sathiya, K. Hemalatha, K. Ramesha, J. -M. Tarascon, A. S. Prakash, Chem. Mater. 24 (2012) 1846–1853. https://doi.org/10.1021/cm300466b

V. K. Kumar, S. Ghosh, S. Biswas, S. K. Martha, J. Electrochem. Soc. 167 (2020 80531. https://doi.org/10.1149/1945-7111/ab8ed5

J. -M. Tarascon, M. Armand. Nature 414 (2011) 171–179. https://doi.org/10.1038/35104644

Y. Bi, J. Tao, Y. Xu, Y. Qi, J. Xiao, Science 370 (2020) 1313–1318. https://doi.org/10.1126/science.abc3167

Y. Chen, S. Wang, Y. Jie, Z. Lei, R. Cao, S. Jiao, Chem. Res. Chinese Univ. 37 (2021) 280–285. https://doi.org/10.1007/s40242-021-0441-y

D. Yuan, X. Hu, R. Mao, X. Ai, H. Yang, Y. Cao, Electrochim. Acta 116 (2014) 300–305. https://doi.org/10.1016/j.electacta.2013.10.211

K. Wang, Z. -G. Wu, X. -D. Guo, B. -B. Xu, B. -H. Zhong, Electrochim. Acta 216 (2016) 51–57. https://doi.org/10.1016/j.electacta.2016.09.003

Y. Wang, G. Hu, X. Qi, Z. Luo, K. Du, J. Power Sources 396 (2018) 639–647. https://doi.org/10.1016/j.jpowsour.2018.06.058

Y. You, S. O. Kim, A. Manthiram, Adv. Energy Mater. 7 (2017) 1601698. https://doi.org/10.1002/aenm.201601698

J. Deng, W. Luo, H. Liu, H. Zhou, S. Dou, Adv. Energy Mater. 8 (2018) 1701610. https://doi.org/10.1002/aenm.201701610

K. Park, B. -C. Yu, J. B. Goodenough., Chem. Mater. 27 (2015) 6682–6688. https://doi.org/10.1021/acs.chemmater.5b02684

P. -F. Wang, Y. You, Y. -X. Yin, Y. -G. Guo, J. Mater. Chem. A 4 (2016) 17660–17664. https://doi.org/10.1039/C6TA07589D




DOI: https://doi.org/10.51316/jca.2021.123

Refbacks

  • There are currently no refbacks.




*******

Index: Google Scholar; Crossref

---------

Vietnam Journal of Catalysis and Adsorption

Address: Room 302  |  C4-5  |  Hanoi University of Science and Technology. 1 Dai Co Viet, Hanoi.

Tel.: ‎‎‎+84. 967.117.098 (Dr. Phượng)  |  Email: editor@jca.edu.vn  |  FB: JCA.VNACA