Size-controlled synthesis of alginate-stabilized Cu2O@Cu nanoparticles: effect of stabilizer agent concentration on particle size

Tuan Le Nghiem Anh, Ngoc Doan Thi Bich, Tho Tran Phuoc, Nhung Nguyen Hong, Du Bui Duy

Abstract


Alginate-stabilized Cu2O@Cu nanoparticles were fabricated by chemical reduction method using nature polymer alginate as a stabilizing agent. Transmission electron microscopy (TEM), X-ray powder diffraction (XRD), infrared (FT-IR) spectrum, and UV-Vis analysis were used to investigate the morphology, size, structure, and stability of the nanoparticles synthesized. The results suggested that concentration of alginate has an effect on particle size of Cu2O@Cu. The particle size of Cu2O@Cu decreased when the alginate concentration increased. The 5% alginate-stabilized Cu2O@Cu nanoparticles have small sizes (5.5±1.6 nm). The first, the as-preprated products formed Cu2O@Cu2O core-shell nanoparticles structure and final, it would be converted to Cu2O@Cu core-shell nanoparticles structure.

Keywords


Alginate-stabilized; Cu2O@Cu nanoparticles; alginate concentration

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References


T. Jay, G. C. Ratiram, V. G. Nilesh, R. R. Alok, Y. Sachin, D. J. Harjeet, J. Exp. Nanosci. 11(11) (2016) 884-900. https://doi.org/10.1080/17458080.2016.1177216

K. Giannousi, G. Sarafidis, S. Mourdikoudis, A. Pantazaki, C. Dendrinou-Samara, Inorg. Chem. 53(18) (2014) 9657-9666. https://doi.org/10.1021/ic501143z

K. P. Ajay, G. C. Ratiram, B. C. Prashant, Y. Sachin, M. Aniruddha, N. S. Vaishali, R. R. Alok, D. J. Harjeet, Mater. Sci. Eng. C 99 (2019) 783-793. https://doi.org/10.1016/j.msec.2019.02.010

B. D. Du, D. V. Phu, L. A. Quoc, N. Q. Hien, J. Nanopart. (2017) Article ID 7056864, 1. https://doi.org/10.1155/2017/7056864

Regmi, J. Bhandari, S. Bhattarai, S. K. Gautam, J. Nep. Chem. Soc. 40 (2019) 5-10. https://doi.org/10.3126/jncs.v40i0.27271

Eivazihollagh, M. Norgren, C. Dahlström, H. Edlund, Nanomater. 8 (2018) 238 (11pp). doi: 10.3390/nano8040238

N. Gu, J. Gao, H. Li, Y. Wu, Y. Ma, K. Wang., Appl. Clay Sci. 79 (2016) 132-133. https://doi.org/10.1016/j.clay.2016.05.017

S. Pandey, J. Ramontja, Int. J. Biol. Macromol. 93 (2016) 712-723. https://doi.org/10.1016/j.ijbiomac.2016.09.033

R. G. Chikte, K. M. Paknikar, Jyutika M. Rajwade, J. Sharma, Appl. Microbiol. Biotechnol. 103(11) (2019) 4605. https://doi.org/10.1007/s00253-019-09740-z

S. Huang, L. Wang, L. Liu, Y.Hou, and L. Li, Agron. Sustain. Dev. 35(2) (2015) 369–400. https://doi.org/10.1007/s13593-014-0274-x

D. Du, D. T. B. Ngoc, N. D. Thang, L. N. A. Tuan, B. D. Thach, N. Q. Hien, Vietnam J. Chem. 57(3) (2019) 318. https://doi.org/10.1002/vjch.201900022

T. B. Ngoc, B. D. Du, L. N. A. Tuan, B. D. Thach, T. P. Tho, D. V. Phu, Adv. Nat. Sci.: Nanosci. Nanotechnol., 2021, 12, 013001. https://iopscience.iop.org/article/10.1088/2043-6262/abebd6/meta

T. B. Ngoc, B. D. Du, L. N. A. Tuan, B. D. Thach, C. T. Kien, D. V. Phu, N. Q. Hien, Indian J. Agric. Res. 54(6) (2020) 802-806. DOI: 10.18805/IJARe.A-582

R. A. Khajouei, J. Keramat, N.R Hamdami, A.-V. Ursu, C. Delattre, C. Laroche, C. Gardarin, D. Lecerf, J. Desbrières, G. Djelveh, P. Michaud, Inter. J. Biol. Macromol. 118 (2018) 1073-1081. DOI : 10.1016/j.ijbiomac.2018.06.154

S. S. Sawant, A. D. Bhagwat, C. M. Mahajan, J. Nano Elec. Phys. 8(1), (2016) 01035 (5pp). Doi: 10.21272/jnep.8(1).01036

H. Khanehzaei, M. B. Ahmad, K. Shameli, Z. Ajdari., Int. J. Electrochem. Sci. 9 (2014) 8189-8198. http://www.electrochemsci.org/papers/vol9/91208189.pdf

J. Diaz-Visurraga, C. Daza, C. Pozo, A. Becerra, C. V. Plessing, A. Garcia, Int. J. Nanomedicine 7 (2012) 3597-3612. DOI: 10.2147/IJN.S32648

S. M. Badawy, R. A. El-Khashab, A. A. Nayl, Bull. Chem. React. Eng. Catal. 10(2) (2015) 169-174. https://doi.org/10.9767/bcrec.10.2.7984.169-174

N. J. Maximino, M. P. Alvarez, R. S. Avila, C. A. Orta, E. J. Regalado, J. Nanomater. (2018) Article ID 9512768 1. https://doi.org/10.1155/2018/9512768

L. Yang, S. P. Li, Y. J. Wang, L. L. Wang, X. C. Bao, R. Q. Yang, Trans. Nonferrous Met. Soc. China. 25 (2015) 3643-3650. https://doi.org/10.1016/S1003-6326(15)64005-5

M. Behera, G. Giri, Mater. Sci.-Poland 32(4) (2014) 702-708. https://doi.org/10.2478/s13536-014-0255-4

V. Andal, G. Buvaneswari, Eng. Sci. Technol. Int. J. 20 (2017) 340-344. https://doi.org/10.1016/j.jestch.2016.09.003




DOI: https://doi.org/10.51316/jca.2021.098

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