Synthesis of S doped TiO2 (S-TiO2) to enhance photocatalytic degradation of Ciprofloxacin in aqueous solutions under visible light

Dang Van Do, Hoa Thi Thanh Duong, Khang Van An Doi, Viet Minh Nguyen

Abstract


In this study, the sol-gel method was successfully used to synthesize S-TiO2 for efficient photocatalytic degradation of Ciprofloxacin solution under visible irradiation. These synthesized materials were characterized by various analytical methods such as XRD, SEM-EDX, FT-IR, and UV diffuse reflectance spectroscopy (DRS). XRD, SEM-EDX, and FT-IR confirmed the successful preparation of these materials. The UV-DSR demonstrated that the material has a lower bandgap in comparison with prime TiO2. The photodegradation results reported that the 0.33S-TiO2 had shown high efficiency in the degradation of Ciprofloxacin in comparison with TiO2. The decomposition of 10 mg/L Ciprofloxacin concentration reached approximately 90% for 150 minutes of visible light irradiation at room temperature at pH = 4.


Keywords


S-TiO2; photodegradation; Ciprofloxacin

Full Text:

PDF

References


J.B. Parsa, T. M. Panah, F. N. Chianeh, Removal of Ciprofloxacin from Aqueous Solution by a Continuous Flow Electro-Coagulation Process., Korean Journal of Chemical Engineering 33(3) (2016) 893–901. https:// 10.1007/s11814-015-0196-6

Q. Wu, Z. Li, H. Hong, K. Yin, L. Tie, Adsorption and Intercalation of Ciprofloxacin on Montmorillonite, Applied Clay Science 50(2) (2010) 204–211. https://doi.org/10.1016/j.clay.2010.08.001

C. Liu, V. Nanaboina, G. V. Korshin, W. Jiang. 2012. Spectroscopic Study of Degradation Products of Ciprofloxacin, Norfloxacin, and Lomefloxacin Formed in Ozonated Wastewater., Water Research 46(16) (2012) 5235-5246. https://doi.org/10.1016/j.watres.2012.07.005

S. Rakshit, D. Sarkar, E. J. Elzinga, P. Punamiya, R. Datta, Mechanisms of Ciprofloxacin Removal by Nano-Sized Magnetite., Journal of Hazardous Materials 246 (2013) 221–226. https://doi.org/10.1016/j.jhazmat.2012.12.032

Y. Fei, Y. Li, S. Han, J. Ma., Adsorptive Removal of Ciprofloxacin by Sodium Alginate/Graphene Oxide Composite Beads from Aqueous Solution., Journal of Colloid and Interface Science 484 (2016) 196–204. https://doi.org/10.1016/j.jcis.2016.08.068

S. Wu, X. Zhao, Y. Li, C. Zhao, Q. Du, J. Sun, Y. Wang, L. Xia, Adsorption of Ciprofloxacin onto Biocomposite Fibers of Graphene Oxide/Calcium Alginate., Chemical Engineering Journal 230 (2013) 389–395. https://10.1016/j.cej.2013.06.072

SK. Bajpai, M. Bajpai, N. Rai., Sorptive Removal of Ciprofloxacin Hydrochloride from Simulated Wastewater Using Sawdust: Kinetic Study and Effect of pH., Water SA 38(5) (2012) 673–682. https://10.4314/WSA.V38I5.4

P W Choo, N M Gantz, Reversible leukopenia related to ciprofloxacin therapy., Southern Medical Journal 83 (5) (1990) 597–598. https:// 10.1097/00007611-199005000-00032

P. Trivedi, D. Vasudevan, Spectroscopic Investigation of Ciprofloxacin Speciation at the Goethite Water Interface., Environmental Science & Technology 41(9) (2007) 3153–3158. https://doi.org/10.1021/es061921y

Lu Lin, Wenbin Jiang, Treatment of Produced Water with Photocatalysis: Recent Advances, Affecting Factors and Future Research Prospects, Catalysts 10(8) (2020) 924. https://doi.org/10.3390/catal10080924

Z. Shayegan, C.S. Lee, F. Haghighat, TiO2 photocatalyst for removal of volatile organic compounds in the gas phase — a review. Chem Eng J 334 (2018) 2408–2439. https://doi.org/10.1016/j.cej.2017.09.153

Y. Shu, J. Ji, Y. Xu, J. Deng, H. Huang, Promotional role of Mn doping on catalytic oxidation of VOCs over mesoporous TiO2 under vacuum ultraviolet (VUV) irradiation., Appl Catal B 220 (2018) 78–87. https://doi.org/10.1016/j.apcatb.2017.08.019

Thanh Tung MH, Dieu Cam NT, Novel direct Z-scheme AgI/N–TiO2 photocatalyst for removal of polluted tetracycline under visible irradiation. Ceram Int 46 (2020) 6012–6021. https://10.1016/j.ceramint.2019.11.058

M. Nasirian, Y. Lin, P. Bustillo-Lecompte, Enhancement of photocatalytic activity of titanium dioxide using non-metal doping methods under visible light: a review., International Journal of Environmental Science and Technology, 15(9) (2017) 2009–2032. https://10.1007/s13762-017-1618-2

John Moma, Jeffrey Baloyi, Modified Titanium Dioxide for Photocatalytic Applications, Photocatalysts - Applications and Attributes https://10.5772/intechopen.79374

Dette C., Pérez-Osorio , TiO2 Anatase with a Bandgap in the Visible Region. Nano Letters 14(11) (2014) 6533–6538. https://10.1021/nl503131s

X. Wang, Y. Tang, M.Y. Lee, T. T. Lim, Solvothermal synthesis of Fe-C co-doped TiO2 nanoparticles for visible-light photocatalytic removal of emerging organic contaminants in water, Applied Catalysis A: General, 409-410 (2011) 257-266. https://doi.org/10.1016/j.apcata.2011.10.011

X. Yang, C. Cao, L. Erickson, K. Klabunde, Photocatalytic degradation of Rhodamine B on C-, S-, N-, and Fe-doped TiO2 under visible-light irradiation, Applied Catalysis B: Environmental 91 (2009) 657-666. https://doi.org/10.1155/2020/4310513

Qingliang Chen, Yulian Zhang, Dongdong Zhang, Yingqin Yang, Ag, and N co-doped TiO2 nanostructured photocatalyst for printing and dyeing wastewater, Journal of Water Process Engineering (2017) 14-20. https://10.1016/j.jwpe.2016.11.007

Masood Hamadaniana, Sajad Karimzadeh, Vahid Jabbari, Synthesis of cysteine, cobalt, and copper-doped TiO2 nano photocatalysts with excellent visible-light-induced photocatalytic activity, Materials Science in Semiconductor Processing (2016) 168-176. https://10.1016/j.mssp.2015.06.085

Vishnu Vijayan Pillai, Sunil P. Lonkar, Facile synthesis of sulfur doped TiO2 nanoparticles with enhanced photocatalytic activity, Conference: International Journal of Materials and Metallurgical (2017).

M. M. Karkare, Choice of precursor not affecting the size of anatase TiO2 nanoparticles but affecting morphology under broader view. International Nano Letters 4(3) (2014). https://10.1007/s40089-014-0111-x

J. He, Y.e- Du, Formation of Anatase/Rutile TiO2 Nanocomposites with Enhanced Photocatalytic Activity. Molecules 24 (2019) 2996.

https://doi.org/10.3390/molecules24162996

Q. Xiang, J. Yu, M. Jaroniec, Nitrogen and sulfur co-doped TiO2 nanosheets with exposed {001} facets: synthesis, characterization and visible-light photocatalytic activity. Phys. Chem. Chem. Phys. 13(11) (2011) 4853–4861. https://10.1039/c0cp01459a

Y.-H. Lin, H.-T. Hsueh, The visible light-driven photodegradation of dimethyl sulfide on S-doped TiO2 : Characterization, kinetics, and reaction pathways. Applied Catalysis B: Environmental 199 (2016) 1–10. https://10.1016/j.apcatb.2016.06.024

Le Thi Hoang Yen, D. Van Thuan, Synthesis of N and S Co-doped TiO2 Nanotubes for Advanced Photocatalytic Degradation of Volatile Organic Compounds (VOCs) in Gas Phase. Topics in Catalysis. (2020). https://10.1007/s11244-020-01347-3




DOI: https://doi.org/10.51316/jca.2021.077

Refbacks

  • There are currently no refbacks.




*******

Index: Google ScholarCrossref

---------

Vietnam Journal of Catalysis and Adsorption

Address: Room 302  |  C4-5  |  Hanoi University of Science and Technology. 1 Dai Co Viet, Hanoi.

Tel.: ‎‎‎+84. 967.117.098 (Dr. Phượng)   Email: editor@jca.edu.vn   FB: JCA.VNACA