Synthesis of TiO2 thin films on different substrates by chemical vapor deposition method

Duc Ta Hong, Quang Phan Ngoc, Thang Vu Viet, Thang Le Minh

Abstract


TiO2 thin films were synthesized by using Chemical Vapor Deposition (CVD) method on different substrates, such as glass, aluminium foil , and ceramic. The samples had been characterized by microscopy analysis, SEM, and EDS. The results show that TiO2 thin films were successfully fabricated and TiO2 nanocrystals with size of 50-100 nm loaded uniformly on surface of different substrates. The photocatalytic activities of all samples were investigated in photo-degradation of methyl orange (MO) under UV light irradiation and was followed by the UV-Vis diffuse reflectance spectroscopy, showing that the conversion of methyl orange achieved the highest percentage of 91% with TiO2 thin film synthesized on the ceramic substrate over 270 minutes of reaction. The hypothetical mechanism explaining this observation is that the surface morphology of ceramic plays a major role in the augmentation of MO molecules adsorption onto the surface of material, thus, improves the dye degradation process.


Keywords


TiO2 thin films; Chemical Vapor Deposition; Methyl orange; Photocatalysis

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References


H. Tada, M. Fujishima and H. Kobayashi, Chemical Society Reviews, 40 (7) (2011) 4232-4243 https://doi.org/10.1039/C0CS00211A

A. L. Linsebigler, G. Lu and J. T. Yates Jr, Chemical Reviews, 95 (3) (1995) 735-758 https://doi.org/10.1021/cr00035a013

S. N. R. Inturi, M. Suidan and P. G. Smirniotis, Applied Catalysis B: Environmental, 180 (2016) 351-361 https://doi.org/10.1016/j.apcatb.2015.05.046

Y. Yan, W. Shi, Z. Yuan, S. He, D. Li, Q. Meng, H. Ji, C. Chen, W. Ma and J. Zhao, Journal of the American Chemical Society, 139 (5) (2017) 2083-2089 https://doi.org/10.1021/jacs.6b12324

K. Hashimoto, H. Irie and A. Fujishima, Japanese journal of applied physics, 44 (12R) (2005) 8269 https://10.1143/JJAP.44.8269

K. Nakata and A. Fujishima, Journal of photochemistry and photobiology C: Photochemistry Reviews, 13 (3) (2012) 169-189 https://doi.org/10.1016/j.jphotochemrev.2012.06.001

Q. Guo, C. Zhou, Z. Ma and X. Yang, Advanced Materials, 31 (50) (2019) 1901997 https://doi.org/10.1002/adma.201901997

S.-C. Jung, S.-J. Kim, N. Imaishi and Y.-I. Cho, Applied Catalysis B: Environmental, 55 (4) (2005) 253-257 https://doi.org/10.1016/j.apcatb.2004.08.009

S. Tanemura, L. Miao, W. Wunderlich, M. Tanemura, Y. Mori, S. Toh and K. Kaneko, Science and Technology of Advanced Materials, 6 (1) (2005) 11-17 https://doi.org/10.1016/j.stam.2004.06.003

M. K Patil, S. Shaikh and I. Ganesh, Current Nanoscience, 11 (3) (2015) 271-285 https://10.2174/1573413711666150212235054

J. M. Rzaij and A. M. Abass, Journal of Chemical Reviews, 2 (2) (2020) 114-121 https://10.33945/SAMI/JCR.2020.2.4

S. C. Jung, B. H. Kim, S. J. Kim, N. Imaishi and Y. I. Cho, Chemical Vapor Deposition, 11 (3) (2005) 137-141 https://doi.org/10.1002/cvde.200406321

A. Dewaele, F. Verpoort and B. Sels, ChemCatChem, 8 (19) (2016) 3010-3030 https://doi.org/10.1002/cctc.201600591

Y. Chimupala, G. Hyett, R. Simpson, R. Mitchell, R. Douthwaite, S. J. Milne and R. D. Brydson, RSC advances, 4 (89) (2014) 48507-48515 https://doi.org/10.1039/C4RA07570F

R. Sonawane, S. Hegde and M. Dongare, Materials chemistry and physics, 77 (3) (2003) 744-750 https://doi.org/10.1016/S0254-0584(02)00138-4

O. Akhavan, Journal of colloid and interface science, 336 (1) (2009) 117-124 https://doi.org/10.1016/j.jcis.2009.03.018

C.-H. Hung and B. J. Mariñas, Environmental science & technology, 31 (5) (1997) 1440-1445 https://doi.org/10.1021/es960685w

D.-J. Lee, S. A. Senseman, A. S. Sciumbato, S.-C. Jung and L. J. Krutz, Journal of agricultural and food chemistry, 51 (9) (2003) 2659-2664 https://doi.org/10.1021/jf026232u

Y. Lai, C. Lin, J. Huang, H. Zhuang, L. Sun and T. Nguyen, Langmuir, 24 (8) (2008) 3867-3873 https://doi.org/10.1021/la7031863

P. Serp, P. Kalck and R. Feurer, Chemical reviews, 102 (9) (2002) 3085-3128 https://doi.org/10.1021/cr9903508

D. Byun, Y. Jin, B. Kim, J. K. Lee and D. Park, Journal of hazardous materials, 73 (2) (2000) 199-206 https://doi.org/10.1016/S0304-3894(99)00179-X

X. Zhang, M. Zhou and L. Lei, Applied Catalysis A: General, 282 (1-2) (2005) 285-293 https://doi.org/10.1016/j.apcata.2004.12.022

H. Lee, M. Y. Song, J. Jurng and Y.-K. Park, Powder technology, 214 (1) (2011) 64-68 https://doi.org/10.1016/j.powtec.2011.07.036

H. Lee, S. Park, S. Kim, B. Kim, H. Yoon, J. Kim and S. Jung, Progress in Organic Coatings, 74 (4) (2012) 758-763 https://doi.org/10.1016/j.porgcoat.2011.09.024

Y. Kuzminykh, A. Dabirian, M. Reinke and P. Hoffmann, Surface and Coatings Technology, 230 (2013) 13-21 https://doi.org/10.1016/j.surfcoat.2013.06.059

J. Yu and X. Zhao, Materials Research Bulletin, 35 (8) (2000) 1293-1301 https://doi.org/10.1016/S0025-5408(00)00327-5

B. Astinchap and K. G. Laelabadi, Journal of Physics and Chemistry of Solids, 129 (2019) 217-226 https://doi.org/10.1016/j.jpcs.2019.01.012

H. Sun, C. Wang, S. Pang, X. Li, Y. Tao, H. Tang and M. Liu, Journal of Non-Crystalline Solids, 354 (12-13) (2008) 1440-1443 https://doi.org/10.1016/j.jnoncrysol.2007.01.108

V. T. Vu, S. Bartling, T. Peppel, H. Lund, C. Kreyenschulte, J. Rabeah, N. G. Moustakas, A.-E. Surkus, H. D. Ta and N. Steinfeldt, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 589 (2020) 124383 https://doi.org/10.1016/j.colsurfa.2019.124383

G. A. Battiston, R. Gerbasi, M. Porchia and A. Marigo, Thin Solid Films, 239 (2) (1994) 186-191 https://doi.org/10.1016/0040-6090(94)90849-4

K. Zimny, T. Roques-Carmes, C. Carteret, M. Stébé and J. Blin, The Journal of Physical Chemistry C, 116 (11) (2012) 6585-6594 https://doi.org/10.1021/jp212428k

R. Acharya and K. Parida, Journal of Environmental Chemical Engineering, 8 (4) (2020) 103896 https://doi.org/10.1016/j.jece.2020.103896

L. Liu and Y. Li, Aerosol and air quality research, 14 (2) (2014) 453-469 https://doi.org/10.4209/aaqr.2013.06.0186

M. Pawar, S. Topcu Sendoğdular and P. Gouma, Journal of Nanomaterials, 2018 (2018) https://doi.org/10.1155/2018/5953609

J. Schneider, M. Matsuoka, M. Takeuchi, J. Zhang, Y. Horiuchi, M. Anpo and D. W. Bahnemann, Chemical reviews, 114 (19) (2014) 9919-9986 https://doi.org/10.1021/cr5001892




DOI: https://doi.org/10.51316/jca.2021.073

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