Synthesis, characterization and catalytic activity estimation of WO3/MeO2 (Me: Zr, Ti, Si) oxides for fructose conversion reaction into 5-hydroxymethylfurfural

Hoa Pham Thi, Ngan Pham Thi Thanh, Binh Nguyen Thanh

Abstract


Series of WO3/MeO2(Me: Zr, Ti, Si) oxides were synthesized by impregnationmethod with 1:9 atomic ration of W:Me.The oxides were characterized by various techniques such as XRD, IR. The XRD patterns showed the crystalline structure of ZrO2, TiO2,WO3 and amorphous of SiO2. They were formed in tetragonal, anatase, monoclinic phase structure. All oxide and mixed oxides were estimated its catalytic activity through fructose conversion into 5-hydroxymethylfurfural in DMSO solvent. The results indicated that all mixed oxides owned good catalytic activity for the reaction in comparison with case of only presence DMSO solvent. Especially, The oxide WO3/ZrO2 showed the best HMF yield, 81,6%, at experimental conditions. This property could be due to the well dispersionand acidity of nano cluster WO3 on the surface s of oxides MeO2.

Keywords


5-hydroxymethylfurfural; fructose; zirconia; titania; tungsten oxit

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References


Andreia A. Rosatella, Svilen P. Simeonov, Raquel F. M. Frade, Carlos A. M. Afonso, Green Chem., 2011, 13, 754. https://doi.org/10.1039/C0GC00401D

Tianfu Wang, Michael W.Nolte, Brent H. Shanks, Green Chem., 2014, 16, 548. https://doi.org/10.1039/C3GC41365A

Zhao S., Cheng M., Li J., Tian J., Wang X., Green Commun., 2011, 47, 2176-2178. https://doi.org/10.1039/C0CC04444J

Hongpeng Yan, Yu Yang, Dongmei Tong, Xi Xiang, Changwei Hu, Catal. Commun., 10 (11), 2009, 1558-156. https://doi.org/10.1016/j.catcom.2009.04.020

Chunyan Fan, Hongyu Guan, Hang Zhang, Jianghua Wang, Shengtian Wang, Xiaohong Wang, Biomass and Bioenergy, 35(7), 2011, 2659-2665. https://doi.org/10.1016/j.biombioe.2011.03.004

Yue-ling CAO, Jun-wei WANG, Mao-qing KANG, Yu-lei ZHU, J. of Fuel Chem. Tech., 44 (7), 2016, 845-852. https://doi.org/10.1016/S1872-5813(16)30038-X

M. Kurhay, Aytekin Aydın M. T., Hoşgün, H. L.,

Dede A., Güven K. Spectro. Acta Part A: Molecular and Biomolecular Spectroscopy, 2018,205, 503-507. https://doi.org/10.1016/j.saa.2018.07.063

D. S. S. Padovini, D. S. L. Pontes, C. J. Dalmaschio, F. M. Pontes, E. Longo, RSC Adv., 2014,4, 38484-38490. https://doi.org/10.1039/C4RA04861J

Ayman M.Mostafa, Samir A.Yousef, Wael H.Eisa, Mahmoud A.Ewaida, Emad A.Al-Ashkar, WO3 quantum dot: J. of Mol. Stru., 1185, 2019, 351-356. https://doi.org/10.1016/j.molstruc.2019.03.007

Guanna Li, Evgeny A Pidko, Emiel J. M. Hensen, ACS Catal., 2016, 6, 4162-4169. https://doi.org/10.1021/acscatal.6b00869

Wang, F.; Shi, A.-W.; Qin, X.-X.; Liu, C.-L.; Dong, W.-S. Carbohydr. Res. 2011, 346, 982. https://doi.org/10.1016/j.carres.2011.03.009

Shimizu, K.-I.; Uozumi, R.; Satsuma, A. Catal. Commun. 2009, 10, 1849. https://doi.org/10.1016/j.catcom.2009.06.012

De, S.; Dutta, S.; Patra, A. K.; Bhaumik, A.; Saha, B. J. Mater. Chem. 2011, 21, 17505. https://doi.org/10.1039/C1JM13229F

Dutta, S.; De, S.; Patra, A. K.; Sasidharan, M.; Bhaumik, A.; Saha, B. Appl. Catal., A 2011, 409−410, 133. https://doi.org/10.1016/j.apcata.2011.09.037

Dutta, A.; Patra, A. K.; Dutta, S.; Saha, B.; Bhaumik, A. J. Mater. Chem. 2012, 22, 14094. https://doi.org/10.1039/C2JM30623A




DOI: https://doi.org/10.51316/jca.2021.054

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