Comparative study on catalytic reactivity of colloidal Ni(0)NPs and Pd(0)NPs towards semi-hydrogenation of alkynes

Phuong Phan Hong, Phuong Nguyen Thi Hong, Hung Lam Hoa, Trung Dang Bao

Abstract


In this study, nickel nanoparticles (Ni(0)NPs) and palladium nanoparticles (Pd(0)NPs) were prepared in neat glycerol under hydrogen pressure by the bottom-up approach. The formation of zero-valent metal nanospheres was evidenced by transmission electron microscopy (TEM) and powder X-ray diffraction (XRD) analyses. Regarding their catalytic behaviors, Ni(0)NPs permitted to obtain the corresponding (Z)-alkenes in the semi-hydrogenation of both internal and terminal alkynes. In contrast, over-hydrogenations of such alkynes towards the alkanes were observed over Pd(0)NPs after only 2 hours of reaction. Interestingly, the catalytic phase of Ni(0)NPs in glycerol could be recycled up to 5 times, preserving their catalytic activity and selectivity.      

Keywords


Nickel; palladium; nanoparticles; catalysis; semi-hydrogenation

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References


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DOI: https://doi.org/10.51316/jca.2021.033

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