PolyTEMPO electrocatalyst for organic electrosynthesis of benzonitrile from benzyl alcohol

Luyen Tran Thi, Benjamin Schille, Robert Francke

Abstract


Requirements for using Poly (2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PolyTEMPO) as an electrocatalyst for the organic electrosynthesis of benzonitrile from benzyl alcohol were investigated. The research results indicated that PolyTEMPO expressed catalytic activity in the electrosynthesis of benzonitrile from benzyl alcohol in the presence of ammonium acetate. The electrosynthesis yield of benzonitrile from benzyl alcohol with PolyTEMPO catalyst reached the maximum value at 35 °C after 18 hours. 

Keywords


PolyTEMPO; Electrocatalyst; Electrosynthesis; Benzonitrile; Benzyl alcohol

Full Text:

PDF

References


Z. Fan, X. Yang, C. Chen, Z. Shen, M. Li, J. Electrochem. Soc., 164(4) (2017) 54-58. https://doi.org/10.1149/2.1561704jes.

X. Y. Qian, S. Q. Li, J. Song, H. C. Xu, ACS Catal., 7(4)(2017) 2730-2734. https://doi.org/10.1021/acscatal.7b00426.

S. Li, L. Cheng, Q. Wu, Q. Zhang, J. Yang, J. Liu, ChemistrySelect, 3(4)(2018) 1268-1274. https://doi.org/10.1002/slct.201702755.

L. T. Tran, B. Schille, R. Francke, Vietnam J. Catal. Ads. 8(4)(2019) 128-131.

B. Schille, N. O. Giltzau, R. Francke, Angewandte Chemie International Edition in English 57(2)(2018) 422-426. https://doi.org/10.1002/anie.201710659.

T. Broese, R. Francke, Org. Let., 18(22)(2016) 5896-5899. https://doi.org/10.1021/acs.orglett.6b02979.




DOI: https://doi.org/10.51316/jca.2021.015

Refbacks

  • There are currently no refbacks.




*******

Index: Google Scholar; Crossref

---------

Vietnam Journal of Catalysis and Adsorption

Address: Room 302  |  C4-5  |  Hanoi University of Science and Technology. 1 Dai Co Viet, Hanoi.

Tel.: ‎‎‎+84. 967.117.098 (Dr. Phượng)  |  Email: editor@jca.edu.vn  |  FB: JCA.VNACA