Metal-organic framework-118 (MOF-118): A heterogeneous catalyst for effective synthesis of pyrroles from aryl amines and 2,5-hexanedione

Chi Nguyen Van, Tung Nguyen Thanh, Huong Nguyen Thi Hong, Thuy Ca Thi, Nam Phan Thanh Son

Abstract


Metal-organic frameworks (MOFs) have been widely used in many applications, particularly catalysis. Here, we reported the synthesis and characteristics of metal–organic framework-118 (MOF-118), which was used for pyrroles synthesis via Paal-Knorr reaction between diketone and aryl amines. It was found that MOF-118 exhibited excellent activity in the reaction between p-anisidine and 2,5-hexanedione. The reaction parameters including catalyst concentrations, reaction temperatures, molar ratio of p-anisidine/2,5-hexadione, and solvents, were systematically investigated. Almost 100% conversion was achieved under the optimized reaction conditions. The reusability of MOF-118 catalyst was studied. Furthermore, we demonstrated that the functional groups on aryl amines have strongly effect on the reaction rate. 

Keywords


Metal-Organic Frameworks; MOF-118; Pyrroles synthesis; 2,5-hexandione; p-anisidine; heterogeneous catalyst

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References


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DOI: https://doi.org/10.51316/jca.2020.061

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