Fischer-Tropsch synthesis over Co/γ-Al2O3 catalyst loaded on ceramic monolith-structured substrate

Uy Do Pham Noa, Huan Nguyen Manh, Loc Hoang Van, Chien Luc Minh, Giang Nguyen Thi Chau, Nhan Truong Van, Binh Phan Minh Quoc, Luong Nguyen Huu, Thuan Huynh Minh

Abstract


Cobalt-based catalyst supported on γ-Al2O3­ was prepared by impregnation method and loaded on ceramic monolith-structured substrate by wash-coating slurry method. Physico-chemical properties of the catalysts were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) specific surface area and H2 temperatured-programmed reduction (H2-TPR). Activity of the catalysts for Fischer-Tropsch synthesis was investigated in a tubular reactor in a temperature range of 200-275 oC at 20 bar and GHSV = 3000 h-1. Co/γ-Al2O3 catalyst loaded on ceramic monolith-structured substrate enhanced efficacy of Fischer-Tropsch synthesis by increasing and stabilizing CO conversion and C5+ selectivity, compared to Co/γ-Al2O3 powder catalyst.

Keywords


Fischer-Tropsch; Monolith structured catalyst; Cobalt-based catalyst; Wash-coating slurry method

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References


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DOI: https://doi.org/10.51316/jca.2020.055

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