Photocatalytic activities of NiFe2O4/nitrogen-doping graphene oxide synthesized by hydrothermal method

Minh Nguyen Ngoc, Nhung Le Thi Cam, Duc Truong Cong, Lieu Nguyen Thi, Thang Nguyen Van, Khieu Dinh Quang, Hoan Nguyen Thi Vuong

Abstract


The NiFe2O4/N-doped GO composites were successfully synthesized by the hydrothermal method from graphene oxide GO, urea, iron nitrat, and niken nitrat. GO was synthesized by a modifìied Hummers,  method. The obtained composites exhibited photocatalytic activities for methylene blue degradation (MB) under visible light irradiation. MB photodegradation efficiency reaches 98% after 240 minutes of illumination. The NiFe2O4/N-doped GO (NF/GO-N) was of better photocatalytic than that of the NF and GO-N. A kinetic model was proposed by the combination of classical Langmuir-Hinshelwood kinetic model, the experimental data fit well the proposed model.

Keywords


Graphene oxide; NiFe2O4/ N-doping GO composites; Photocatalysts; Hydrothermal method

Full Text:

PDF

References


S. Bai, X. Shen, X. Zhong, Y. Liu, G. Zhu, X. Xu Chen K, One-pot solvothermal preparation of magnetic reduced graphene oxide-ferrite hybrids for organic dye removal, Carbon, 50, 2012, pp. 2337–2346. https://doi.org/10.1016/j.carbon.2012.01.057.

W. Lixia, L. Jiangchen, et al. Adsorption capability for Congo red on nanocrystalline MFe2O4 (M=Mn, Fe, Co, Ni) spinel ferrites, Chemical Engineering Journal 181, 2012, 72-79. https://doi.org/10.1016/J.CEJ.2011.10.088.

S. Suresh, A. Prakash, D. Bahadur, The role of reduced graphene oxide on the lectrochemical activity of MFe2O4 (M = Fe, Co, Ni and Zn) nanohybrids, Journal of Magnetism and Magnetic Materials , 2017, http://dx.doi.org/10.1016/j.jmmm.2017. 08.034

X. Wu, W. Wang, F.Li, S. Khaimanov, N. Tsidaeva, M. Lahoubi, PEG-assisted hydrothermal synthesis of CoFe2O4 nanoparticles with enhanced selective adsorption properties for different dyes, Appl. Surf. Sci, 389, 2016, 1003–1011. DOI: 10.1016/j.apsusc.2016.08.053

Y. Fu and X. Wang, Magnetically Separable ZnFe2O4–Graphene Catalyst and its High Photocatalytic Performance under Visible Light Irradiation, Ind. Eng. Chem. Res. , 50, 2011, 7210-7218. https://doi.org/10.1021/ie200162a

Y. Fu, Q. Chen, M. He, Y. Wan, X. Sun, H. Xia and X. Wang, Copper Ferrite-Graphene Hybrid: A Multifunctional Heteroarchitecture for Photocatalysis and Energy Storage, Ind. Eng. Chem. Res. , 51, 2012, 11700-11709. https://doi.org/10.1021/ie301347j.

Y. Fang, R. Wang, G. Jiang, H. Jin, Y. Wang, X. Sun, Wang and T. Wang, CuO/ TiO2 nanocrystals grown on graphene as visible-light responsive photocatalytic hybrid materials, Bull. Mates. Sci, 35, 2012, 495-499.

Y. Hou, X. Li, Q. Zhao and G. Chen, ZnFe2O4 multi-porous microbricks/ graphene hybrid photocatalyst: Facile synthesis, improved activity and photocatalytic mechanism, Appl. Catal, B, 142–143, 2012, 80 – 88. DOI: 10.1016/j.apcatb.2013.04.062

L. Sun, R. Shao, L.T. and Z. Chen, Synthesis of ZnFe2O4/ZnO nanocomposites immobilized on graphene with enhanced photocatalytic activity under solar light irradiation, J. Alloys Compd, 564, 2013, 55–62. DOI: 10.1016/j.jallcom.2013.02.147

S. V Kumar, N. Huang, N. Yusoff and H. Lim, High performance magnetically separable graphene/zinc oxide nanocomposite, Mater. Lett, 93, 2013, 411–414. DOI: 10.1016/j.matlet.2012.09.089

L. Ai, C.Zhang, Z. Chen, J. Hazard, Removal of methylene blue from aqueous solution by a solvothermal-synthesized graphene/magnetite composite, Mater. 192 (3), 2011, 1515–1524. doi: 10.1016 / j.jhazmat.2011.06.068.

Fu Y, Chen H, Sun X, Wang X, Combination of cobalt ferrite and graphene: High-performance and recyclable visible-light photocatalysis, Appl. Catal. B, 111–112, 2012, 280–287. https://doi.org/10.1016/j.apcatb.2011.10.009.

L.P. Lingamdinne, Y.L. Choi, I.S. Kim, Y.Y. Chang, J.R.Koduru, J.K. Yang, Porous graphene oxide based inverse spinel nickel ferrite nanocomposites for the enhanced adsorption removal of arsenic, RSC Adv. , 6, 2016, 73776–73789. https://doi.org/10.1039/C6RA10134H

Y.K. Penke, G. Anantharaman, J. Ramkumar, K.K. Kar, RSC Adv., 6, 2016, 55608–55617. DOI: 10.1039/C6RA06332b.

Đỗ Thị Phương Hoàng, Nguyễn Thị Thúy, Nguyễn Thị Hà, Trần Thị Hồng Điệp, Nguyễn Ngọc Minh, Nguyễn Hoàng Anh, Lê Thị Thanh Thúy, Nguyễn Văn Thắng, Nguyễn Thị Vương Hoàn, Tổng hợp và tính chất xúc tác quang của vật liệu composite NiFe2O4/ graphen oxit biến tính bởi nitơ, Tạp chí XTHP, Số 2, Tập 9, 2020.

W.S. Hummers Jr., R. E. Offerman (1958), Preparation of Graphitic Oxide, J.A. Chemical Society, 80, 1339-1339. http://dx.doi.org/ 10.1021/ja01539a017

X. J. Zhang, G. S. Wang, W. Q. Cao, Y. Z. Wei, J. F. Liang, Lin Guo and and M. S. Cao, ACS Appl. Mater. Interfaces, 2014, 6, 7471-7478. DOI: 10.1021/ am500862g.

R. Singh, M. Kumar, L. Tashi, H. Khajuria and H.N. Sheikh, Hydrothermal synthesis of nitrogen doped graphene supported cobalt ferrite (CoFe2O4/NG) as photocatalyst for the methylene blue dye degradation, Nanochemistry Research, 3, 2018, pp. 149-159. DOI: 10.22036/ncr.2018.02.004.

M. M. Mokhtar, M.A. Mousa, M. Khairy and A.A. Amer, Nitrogen graphene: A new and exciting generation of visible light driven photocatalyst and energy storage application, ACS Omega, 3, 2018, pp. 1801-1814. DOI: 10.1021/acsomega.7b01806.

C. Suwanchawalit, and V. Somjit, Hydrothermal synthesis of magnetic CoFe2O4-Graphene nanocomposite with enhanced photocatalytic performance, Digest. J. Nanomater. Biostruc, 10, 2015, pp. 769-777.

L. Sun, R. Shao, L.T. and Z. Chen, Synthesis of ZnFe2O4/ZnO nanocomposites immobilized on graphene with enhanced photocatalytic activity under solar light irradiation, J. Alloys Compd, 564, 2013, 55–62. DOI: 10.1016/j.jallcom.2013.02.147

P. Ramesh Kumar, Enhanced properties of porous CoFe2O4–reduced graphene oxide composites with alginate binders for Li-ion battery applications, New J. Chem, 2014, 38, 3654-3361. DOI: 10.1039/c4nj00419a.

G. Xiaojun, Fast degradation of Acid Orange II by bicarbonate-activated hydrogen peroxide with a magnetic S-modified CoFe2O4 catalyst, Journal of the Taiwan Institute of Chemical Engineers, 2015, 1–11. DOI: 10.1016/j.jtice.2015.03.039.

Dafeng Zhang, One-step combustion synthesis of CoFe2O4–graphene hybrid materials for photodegradation of methylene blue, Materials Letters, 113, 2013, 179–181. DOI: 10.1016/j.matlet.2013.09.088

Y. Fu, Q. Chen, M. He, Y. Wan, X. Sun, H. Xia and X. Wang, Copper Ferrite-Graphene Hybrid: A Multifunctional Heteroarchitecture for Photocatalysis and Energy Storage, Ind. Eng. Chem. Res. , 51, 2012, 11700–11709. https://doi.org/10.1021/ie301347j.

M. Kiani, J. Zhang, J. Fan, H. Yang, G. Wang, J. Chen, R. Wang, Spinel nickel ferrite nanoparticles supported on nitrogen doped graphene as efficientelectrocatalyst for oxygen reduction in fuel cells, Mater. Express, Vol. 7, No. 4, 2017, pp. 261-272. DOI: 10.1166/mex.2017.1376




DOI: https://doi.org/10.51316/jca.2020.049

Refbacks

  • There are currently no refbacks.




*******

Index: Google ScholarCrossref

---------

Vietnam Journal of Catalysis and Adsorption

Address: Room 302  |  C4-5  |  Hanoi University of Science and Technology. 1 Dai Co Viet, Hanoi.

Tel.: ‎‎‎+84. 967.117.098 (Dr. Phượng)   Email: editor@jca.edu.vn   FB: JCA.VNACA