Study on synthesis of mesoporous carbon from MOF-199 metal-organic framework as potential adsorbent

Duy-Anh Nguyen, Duc-Duong La, Ngoc-Tuan Truong, Thanh-Bac Le, Van-Phuoc Mai, Tuan Anh Doan

Abstract


Porous carbon material is one of the most common and very important for various applications thank to its high surface area and adsorption capability. In this study, mesoporous carbon was prepared by thermal decomposition of copper-based metal-organic framework MOF-199 under inert atmosphere and followed by immersing in diluted HNO3 solution in order to remove metal/metal oxide and activation of the resultant porous carbon. Scanning electron microscopy (SEM) revealed that as-prepared material remained intact octahedral morphology of pre-pyrolysis MOF structure, and product has spongy structure with specific surface area of 375 m2/g as measured using N2 adsorption isotherm (BET), which can be employed as an effective adsorbent.

Keywords


mesoporous carbon; metal-organic framework; adsorbent

Full Text:

PDF

References


Hao Li, Kecheng Wang, Yujia Sun, Christina T. Lollar, Jialuo Li, Hong-Cai Zhou, Recent advances in gas storage and separation using metal-organic frameworks, materialstoday, 21, 2018, 108-121.

Amarajothi Dhakshinamoorthy, Zhaohui Li, Hermenegildo Garcia, Catalysis and photocatalyst by metal organic frameworks, Chemical Society Reviews, 47,2018, 8134-8172.

Hoai Phuong Nguyen Thi, Ha Duc Ninh, Chinh Van Tran, Bac Thanh Le, Sheshanath V. Bhosale, Duong Duc La, Size-control and surface modification of flexible metal-organic framework MIL-53(Fe) by polyethyleneglycol for 5-fluorouracil anticancer drug delivery, Chemistry Select, 4, 2019, 2333-2338.

Meili Ding, Xuechao Cai, Hai-Long Jiang, Improving MOF stability: approaches and applications, Chemical Science, 10, 2019, 10209-10230.

Imran Ali, Al Arsh Basheer, X.Y. Mbianda, Alexander Burakov, Evgeny Galunin, Irina Burakova, Elina Mkrtchyan, Alexey Tkachev, Vladimir Grachev, Graphene based adsorbents for remediation of noxious pollutants from wastewater, 127, 2019, 160-180.

Xuemei Ren, Changlun Chen, Masaaki Nagatsu, Xiangke Wang, carbon nanotubes as adsorbents in environmental pollution management: A review, Chemical Engineering Journal, 2, 2011, 395-410.

Parya Kahrizi, Fatemeh S. Mohseni-Shahri, Farid Moeinpour, Adsorptive removal of cadmium from aqueous solutions using NiFe2O4/hydroxyapatite/graphene quantum dots as a novel nano-adsorbent, 8, 2018, 441-452

Bo Liu, Hiroshi Shioyama, Tomoki Akita, Qiang Xu, Metal-organic framework as a template for porous carbon synthesis, J. Am. Chem. Soc. 130, 2008, 5390-5391.

Thuan Van Tran, Duyen Thi Cam Nguyen, Hanh T.N. Le, Oanh T.K. Nguyen, Vinh Huu Nguyen, Thuong Thi Nguyen, Long Giang Bach and Trinh Duy Nguyen, A hollow mesoporous carbon from metal-organic framework for robust adsorbability of ibuprofen drug in water, R. Soc. Open Sci. 6, 2019, 190058.




DOI: https://doi.org/10.51316/jca.2020.016

Refbacks

  • There are currently no refbacks.




*******

Index: Google Scholar; Crossref

---------

Vietnam Journal of Catalysis and Adsorption

Address: Room 302  |  C4-5  |  Hanoi University of Science and Technology. 1 Dai Co Viet, Hanoi.

Tel.: ‎‎‎+84. 967.117.098 (Dr. Phượng)  |  Email: editor@jca.edu.vn  |  FB: JCA.VNACA