Metal-Organic Framework Fe3O(BPDC)3 as an efficient catalyst for the oxidative couling reaction of benzaldehyde and (E)-1-phenylethan-1-one O-acetyl oxime

Son Doan Hoai, Tram Van Thi, Giao Dang Huynh, Nhan Le Thi Hong, Nam Phan Thanh Son

Abstract


A porous crytalline metal-organic framework Fe3O(BPDC)3 was synthesized, and its properties were characterized by various techniques, including X-ray powder diffraction (PXRD), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen physisorption measurements. The Fe3O(BPDC)3 was used as an efficient catalyst for the oxidative coupling reaction of benzaldehyde and (E)-1-phenylethan-1-one O-acetyl oxime to form 2,4,6-triphenylpyridine as desired product. The reaction could proceed readily, with more than 83 % reaction yield being achieved after 360 min at 140 oC in the presence of 10 mol% Fe3O(BPDC)3) catalyst and Di-tert-butyl peroxide as an oxidant. This Fe-MOF exhibited higher activity than other MOFs and traditional homogeneous catalysts in the oxidative coupling reaction. The transformation could only proceed to obtain main product in the presence of Fe3O(BPDC)3.

Keywords


acetyl oxime; benzaldehyde; di-tert-butyl peroxide; Fe3O(BPDC)3; Arylpyridines

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References


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DOI: https://doi.org/10.51316/jca.2020.005

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