Study on the synthesis of graphene/Fe2O3-TiO2@porphyrin hybrid composite and its application as photocatalyst for dyeing wastewater treatment

Tuan Truong Ngoc, Giang Nguyen Thi, Phuong Nguyen Thi Hoai, Hien Ho Phuong, Phuong Nguyen Thi Hong, Lam Tran Dai, Duong La Duc

Abstract


Graphene/Fe2O3-TiO2@porphyrin composite was successfully fabricated via self-assembled approach. The synthesized material was fully characterized by UV-Vis, SEM, XRD, photoluminescence, and FT-IR techniques. The graphene@Fe2O3-TiO2@porphyrin composite exhibited uniform incorporation of Fe2O3-TiO2 particles and aggregated nanorod porphyrin on the graphene surface. The resultant graphene@Fe2O3-TiO2@porphyrin composite reveal high photocatalytic performance toward RhB degradation under silmulated sunlight irradiation, which can be utilized as a promising photocatalyst for green environment remediation.

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References


Lellis, B., et al., Effects of textile dyes on health and the environment and bioremediation potential of living organisms. Biotechnology Research and Innovation, 2019. 3(2): p. 275-290.

Ren, N.-Q., et al., A review on treatment methods of dye wastewater. Huagong Xuebao/CIESC Journal, 2013. 64: p. 84-94.

Pawar, M., S. Topcu Sendoğdular, and P.J.J.o.N. Gouma, A Brief Overview of TiO2 Photocatalyst for Organic Dye Remediation: Case Study of Reaction Mechanisms Involved in Ce-TiO2 Photocatalysts System. 2018. 2018.

La, D.D., et al., Fabrication of a TiO2@ porphyrin nanofiber hybrid material: a highly efficient photocatalyst under simulated sunlight irradiation. 2017. 8(1): p. 015009.

Kim, H.J., et al., Assembly and X-ray crystal structures of heterometallic multiporphyrins with complementary coordination between ruthenium (II) and tin (IV) porphyrins. 2019. 488: p. 1-7.

Windle, C.D., et al., Comparison of rhenium–porphyrin dyads for CO 2 photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy. 2015. 6(12): p. 6847-6864.

Alka, A., V.S. Shetti, and M.J.C.C.R. Ravikanth, Coordination chemistry of expanded porphyrins. 2019. 401: p. 213063.

La, D.D., et al., Arginine-induced porphyrin-based self-assembled nanostructures for photocatalytic applications under simulated sunlight irradiation. 2017. 16(2): p. 151-154.

Ge, R., et al., Highly efficient graphene oxide/porphyrin photocatalysts for hydrogen evolution and the interfacial electron transfer. 2016. 187: p. 67-74.

Ussia, M., et al., Freestanding photocatalytic materials based on 3D graphene and polyporphyrins. 2018. 8(1): p. 5001.

Bạch Xuân Hiếu, T.N.T., Lê Hải Khoa, Nguyễn Thị Hoài Phương, Nguyễn Thị Hồng Phượng, Đặng Trung Dũng, Trần Xuân Tùng, Trần Văn Chinh, Lã Đức Dương, Fabrication of porphyrin@TiO2-graphen hybrid materials and investigation of photocatalytical behavior toward RhB degradation. Vietnam Journal of Catalysis and Adsorption, 2019. 8(2): p. 57-62.

Truong Ngoc Tuan, N.T.T., Tran Van Chinh, La Duc Duong, Nguyen Thi Hong Phuong, Nguyen Thi Hoai Phuong, Study on the synthesis of graphene/Fe2O3-TiO2 composite and its aplication as photocatalyst for waste treatment. Vietnam Journal of Catalysis and Adsorption, 2019. 8(1): p. 109-113.

La, M.D.D., S. Bhargava, and S.V. Bhosale, Improved and a simple approach for mass production of graphene nanoplatelets material. ChemistrySelect, 2016. 1(5): p. 949-952.

Tian, J. and W.J.P.i.P.S. Zhang, Synthesis, Self-assembly and Applications of Functional Polymers Based on Porphyrins. 2019.

Min, K.S., et al., Synthesis of new TiO2/porphyrin-based composites and photocatalytic studies on methylene blue degradation. 2019. 160: p. 37-47.

Li, X., et al., Dendritic α-Fe2O3/TiO2 nanocomposites with improved visible light photocatalytic activity. 2016. 18(13): p. 9176-9185.

Zhu, K., et al., The study of a novel cobalt-implanted pyridylporphyrin/graphene oxide nanohybrid for enhanced photocatalytic hydrogen evolution and its electron transfer mechanism. 2018. 10(39): p. 18635-18641.

Zhou, X.T., H.B. Ji, and X.J. Huang, Photocatalytic degradation of methyl orange over metalloporphyrins supported on TiO2 Degussa P25. Molecules, 2012. 17(2): p. 1149-58.

Zhang, J.-J., et al., Three-dimensional Fe2O3–TiO2–graphene aerogel nanocomposites with enhanced adsorption and visible light-driven photocatalytic performance in the removal of RhB dyes. Journal of Industrial and Engineering Chemistry, 2018. 61: p. 407-415.

Duc La, D., et al., Fabrication of a TiO2@porphyrin nanofiber hybrid material: a highly efficient photocatalyst under simulated sunlight irradiation. Advances in Natural Sciences: Nanoscience and Nanotechnology, 2017. 8(1): p. 015009.

La, D.D., et al., Fabrication of a Graphene@TiO2@Porphyrin Hybrid Material and Its Photocatalytic Properties under Simulated Sunlight Irradiation. ChemistrySelect, 2017. 2(11): p. 3329-3333.




DOI: https://doi.org/10.51316/jca.2020.002

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