Synthesis and application of M-BTC (M = Fe, Ni, Mn) materials as highly efficient photocatalyst in the photocatalytic degradation of reactive yellow 145 dye

Manh Nguyen Ba, Giang Le Ha, Trang Pham Thi Thu, My Pham Thi Ha, Thanh Duong Anh, Dung Le Van, Giang Pham Thi Thu, Hoa Vu Thi, Quang Nguyen Ke, Phuong Dang Tuyet

Abstract


In this study, we synthesized a series of metal organic frameworks (MOFs) of 1,3,5-benzenetricarboxylate (M-BTC), where M = Fe2+, Ni2+ and Mn2+ by hydrothermal treatment with a microwave assisted method. M-BTC samples were characterized by XRD, FTIR, SEM and BET. SEM-image result showed nano M-BTC particles size of 20-40 nm. Samples M-BTC showed the high surface area (1301 m2/g) and pore volume (1.12 cm3/g). The samples M-BTC were tested for the photocatalytic degradation of reactive dye (Reactive Yellow 145) in water. The M-BTC materials exhibited high photocatalytic activity. Thus, at the pH of 6.5 and the high initial concentration of 100 mg RY-145/L, removal efficiency reached the value of 98.63% after 120 min reaction. Moreover, nanomaterial Fe-BTC also showed high RY-145 dye removal efficiency after 4 catalytic regeneration.

Keywords


Fe-BTC; Ni-BTC. Mn-BTC; RY-145; photocatalyst

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References


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DOI: https://doi.org/10.51316/jca.2021.146

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